MAKİNE ÖĞRENMESİNİN ÇOCUK RUH SAĞLINA ETKİSİ
نویسندگان
چکیده
منابع مشابه
Bis(dicyclohexylphosphino)ethane. Structures of [RuH(dcpe)2]+[BPh4]- and of the Zwitterionic {(η6-C6H5)BPh3}RuH(dcpe)
Two hydrido ruthenium complexes could be isolated from the reaction between RuCl2(DMSO)4 (DMSO ) dimethyl sulfoxide) and the chelating 1,2-bis(dicyclohexylphosphino)ethane (dcpe) and [BPh4]. These are [RuH(dcpe)2][BPh4] with a five-coordinate, 16 valence electron cation and the neutral zwitterionic 18 valence electron compound {(η-C6H5)BPh3}RuH(dcpe). The relative amounts of these products depe...
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متن کاملSynthesis and reactivity of ruthenium tridentate bis-phosphinite ligand complexes.
The tridentate ligands E(CH2CH2OPiPr2)2 (E = NH 1, E = S 2) were employed in the synthesis of a number of ruthenium complexes. Reaction of these ligands with (Ph3P)3RuCl2 afforded the dimers [Ru(HN(CH2CH2OPiPr2)2)Cl(μ-Cl)]2 (3) and [(Ru(E(CH2CH2OPiPr2)2))2(μ-Cl)3][X] (E = NH, X = PF64, E = S, X = Cl 5), respectively. Using (Ph3P)3RuHCl in reactions with 1 gave Ru(NH(CH2CH2OPiPr2)2)(PPh3)HCl (6)...
متن کاملClassical and non-classical phosphine-Ru(II)-hydrides in aqueous solutions: many, various, and useful.
Hydrogenation of the water-soluble [{RuCl(2)(mtppms)(2)}(2)] (mtppms = monosulfonated triphenylphosphine) was studied in aqueous solutions in the presence of excess mtppms both with H(2) and with aqueous HCOONa. Depending on the reductant, the pH and H(2) pressure altogether nine hydride species were identified. In acidic solutions at 1 bar H(2) pressure the known [RuHCl(mtppms)(3)] (1) and [{R...
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ژورنال
عنوان ژورنال: Asosjournal
سال: 2023
ISSN: ['2148-2489']
DOI: https://doi.org/10.29228/asos.69003